There is a possibility to connect serial with RS323,RS485 or RS422.
The 7i66 is connected to 7i44 and this is connected to 5i23.
But all the ports on 7i44 are most likely gonna be used up.
On the 5i23 P3 is still available.
You can get 10V but it needs an op-amp (to change the 0..5V analog to 0..10V)
or some kind of level translator for the PWM before filtering. (our SPINX1 does this)
Heres an example schematic for a 7I66 output filter: